Table 3. Metrological and electrochemical parameters of the electrodes.
|
Parameter |
Equation |
Description |
|
Limit of detection |
S=∆I/∆C |
S – sensitivity [A/M], I – current [А], С – concentration |
|
Limit of detection |
LOD=k*σ/m |
σ - standard deviation of control measurement, m – calibration curve slope, k – parameter corresponding to statistical significance, LOD [μg/ml] |
|
Limit of quantification |
LOQ=10*σ/m |
σ - standard deviation of control measurement, m – calibration curve slope, LOQ [μg/ml] |