Luminescent Properties of Composite Systems Based on Polystyrene and Erbium(III) Phthalocyaninates in Near IR Spectral Region

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Published: Sep 7, 2018
DOI: https://doi.org/10.18097/BMCRM00029
Keywords:
phthalocyanines rare earth elements erbium sandwich complexes luminescence near IR region

Main Article Content

I.A. Belogorokhov
Institute of Physiologically Active Compounds of the Russian Academy of Sciences, 1 Severny proezd, Moscow region, Chernogolovka, 142432 Russia
L.I. Belogorokhova
Department of Physics, Lomonosov Moscow State University, 1 Leninskie Gory, Moscow, 119991 Russia
Yu.V. Ryabchikov
Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninsky av., Moscow, 119333 Russia
V.E. Pushkarev
Institute of Physiologically Active Compounds of the Russian Academy of Sciences, 1 Severny proezd, Moscow region, Chernogolovka, 142432 Russia

Abstract

Composite materials based on polystyrene and ErIII phthalocyaninates of single-, double- and triple-decker structure were obtained, and their spectral luminescent characteristics in the near-IR (NIR) range were studied. All the ErIII complexes in these composites reveal 4f photoluminescence (PL), which is observed at 1550 nm for mono- and tris(phthalocyaninate), whereas in the case of bis(phthalocyaninate), the PL maximum is shifted to the short-wavelength region and appears at 1440 nm. A comparative analysis of the properties of composites and individual phthalocyanine compounds in films and solutions was carried out. In the case of a single-decker complex, this emission was detected for the first time in the polystyrene matrix, while for individual ErIII mono(phthalocyaninates), this process was not observed earlier.

Article Details

How to Cite
Belogorokhov, I., Belogorokhova, L., Ryabchikov, Y., & Pushkarev, V. (2018). Luminescent Properties of Composite Systems Based on Polystyrene and Erbium(III) Phthalocyaninates in Near IR Spectral Region. Biomedical Chemistry: Research and Methods, 1(3), e00029. https://doi.org/10.18097/BMCRM00029
Issue
Vol. 1 No. 3 (2018)
Section
EXPERIMENTAL RESEARCH

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